Enhanced superconductivity of the Ti - Zr alloys in the high-pressure BCC phase
I. O. Bashkin, V. G. Tissen, M. V. Nefedova, A. Schiwek+, W. B. Holzapfel+, E. G. Ponyatovsky
Institute of Solid State Physics RAS
142432 Chernogolovka, Moscow district, Russia
+Fachbereich 6 - Physik, Universität-GH Paderborn
D-33095 Paderborn, Germany
PACS: 64.70.Kb, 74.62.-c
Abstract
A high-pressure study of the crystal structure and
superconductivity of Ti - Zr alloys demonstrates an increase of
the ω - β transition pressure from about 30 to
43-57 GPa when the titanium content in the alloys increases from 0
to 50 at.%. The isobaric values of the BCC β- phase
superconducting temperature (at 46 GPa) increase from 5.7 to more
than 15 K between 0 and 50 at.% Ti, the latter value being the
absolute maximum for BCC d- metal alloys. These data
correlate with the earlier assumption of an s-d electron
transfer in Zr under pressure.