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VOLUME 51 (1990) | ISSUE 1 | PAGE 17
Experimental study of a sequence of quantum bifurcations leading to the crossover of a rotational multiplet
The "crossover" of the energy spectrum of a molecule during rotational excitation corresponds to a series of bifurcations in the classical limiting problem. The sequence and type of these bifurcations are determined by the symmetry conditions. This effect is studied in the high-resolution spectrum of R 3_ band of the v3 state of the CF4 molecule.