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VOLUME 52 (1990) | ISSUE 5 | PAGE 890
Observation of magnetic dipole and electric dipole electron transitions in the ground multiplet of the rare-earth ion in TmFeO3
Magnetic dipole and electric dipole rare-earth modes observed in the submillimeter absorption spectra and the far-IR reflection spectra of the orthoferrite TmFe03 stem from electron transitions within the ground multiplet of the Tm3 + ion. The symmetry is determined. The observed electronic excitations are classified.