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VOLUME 61 (1995) | ISSUE 9 |
PAGE 768
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Nature and charge states of a Ga impurity in PbTe
Vasil'ev A. N. , Volkov B. A. , Voloshok T. N. , Kuvshinnikov S. V.
The temperature dependence of the resistivity ρ and the magnetic susceptibility χ has been measured during low-intensity illumination of a compensated PbTe(0.3 at. % Ga) single crystal, which exhibits a persistent photoconductivity. The p(T) dependence is exponential at Γ^72 K, deviating toward smaller values at low temperatures. The magnetic susceptibility obeys a Curie-Weiss law over the temperature interval 4.2«Γ=£45 К with a cutoff temperature Θ = -5.8 К. There is a sharp increase in the paramagnetic component of χ in the temperature interval 45=еГ=£72 K, in the diamagnetic region. At higher temperatures, the diamagnetic susceptibility falls off monotonically. The temperature dependence χ(Τ) is interpreted in terms of a mixed valence of Ga in PbTe and the existence of an s1p2 paramagnetic state of this impurity. © 1995 American Institute of Physics.
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