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VOLUME 59 (1994) | ISSUE 1 | PAGE 24
Splitting of polarized impurity-fluorescence bands in the steady-state spectrum of an isotropic solution
A difference is predicted between the peaks, vvv and vVH, of the polarized components JVy{v) and JVH(v) in the steady-state spectrum of impurity fluorescence in an isotropic solution. This difference would result from a temporal correlation between an orientational Brownian diffusion of excited fluorescing molecules and a structural relaxation of the surrounding matrix molecules.