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VOLUME 59 (1994) | ISSUE 4 |
PAGE 262
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Superconductivity in YBa2Cu3Ox
Blackstead H. A., Dow J. D.
Neutral oxygen, or the pairing of holes via O-2, is identified as the essential ingredient of superconductivity in YBa2Cu30^. "Fabrication" of superconducting YBa2Cu3Ox from semiconducting PrBa2Cu307 in a thought experiment or Gedankenexperiment leads to (i) prediction of the range of superconducting compositions 6.5<x<7, (ii) an understanding of the two-stepped character of the critical temperature Tc(x), (iii) a natural explanation of photoinduced superconductivity, (iv) elucidation of the major doping studies, (v) a derivation of Tokura's empirical rule relating the critical oxygen composition xc of the alloy õ(øÁ27÷Á2_2>,)óÉÚïÈ to the critical La content yc:xc=6.5 + 2yc, and (vi) identification of the charge-reservoir layers (the layers containing the Cu-O chains) as the root of superconductivity.
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