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VOLUME 41 (1985) | ISSUE 5 | PAGE 213
Bunching of cerium valence in mixed-valence compounds
Experiments reveal that cerium has a valence ~3.13, —3,27, or —3.39 in intermetallic compounds of mixed valence. The effect is explained on the basis that the different valence values correspond to different final states of a 4f electron. It may be possible to use this bunching effect to identify the final state of the 4/ electron in a mixed-valence phase.