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VOLUME 86 (2007) | ISSUE 1 | PAGE 26
Dipolar temperature and Multiple Quantum NMR Dynamics in Dipolar Ordered Spin Systems
Abstract
We investigate analytically and numerically the Multiple Quantum (MQ) NMR dynamics in systems of nuclear spins 1/2 coupled by the dipole-dipole interactions in the case of the dipolar ordered initial state. We suggest a new method of MQ NMR based on the measurement of the dipolar temperature in the quasi-equilibrium state which establishes after the time of order ωloc-1 (ωloc is the dipolar local field) after the MQ NMR experiment. Many-spin clusters and correlations are created faster in such experiment than in the usual MQ NMR experiments and can be used for the investigation of many-spin dynamics of nuclear spins in solids.