Phonon spectrum in the vicinity of the phase transition from a crystal to a nematic liquid crystal, and the order parameter
Afanas'eva N.I., Burlakov V.M., Zhizhin G.N.
The immediate vicinity of the crystal-nematic liquid crystal phase transition wa; investigated for the first time by using the long-wave IR absorption spectrum. From the temperature dependence of the integrated intensity of the 24 cm 1 phonon bend in the spectrum, we obtain for the order parameter at T< Tu a variation that agrees with the Landau theory.