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VOLUME 23 (1976) | ISSUE 10 | PAGE 569
Singularities of the SF6 absorption spectrum at high IR intensities
It is demonstrated experimentally that the frequency of the maximum of SF6 molecule absorption shifts to the long-wave region at high incident-radiation energies and at IR pulse durations exceeding the time of the vibrational-translation relaxation. An explanation is offered for the observed absorption-spectrum singularities.