Enhanced Raman scattering provided by fullerene nanoclusters
B. S. Razbirin, E. F. Sheka+, A. N. Starukhin, D. K. Nelson, P. A. Troshin*, R. N. Lyubovskay*
A.F. Ioffe Physical-Technical Institute, RAS, 194021 St.Petersburg, Russia
+Peoples' Friendship University of the Russian Federation, 117198 Moscow, Russia
*Institute of Problems of Chemical Physics, RAS, 142432 Chernogolovka, Moscow reg., Russia
PACS: 33.20.-t, 61.46.+w, 78.30.Na, 78.45.+h
Abstract
Observed in crystalline solutions of fullerenes in toluene and
carbon tetrachloride, two new nonlinear optic effects are reported. Both are
provided by a self-clustering of the solute molecules and are referred to
fullerene enhanced Raman scattering (FERS) and solvent enhanced luminescence
(SEL). The effects are induced by the excitation of charge transfer states of
the fullerene nanoclusters that makes the latter to act as amplifiers of
local electric fields.