Polarization switching kinetics of ferroelectric nanostructures of vinylidene fluoride-trifluoroethylene copolymer
R. V. Gaynutdinov, O. A. Lysova, S. G. Yudin, A. L. Tolstikhina, A. L. Kholkin+, V. M. Fridkin
Institute of Crystallography RAS, 119333 Moscow, Russia
+Department of Ceramics, University of Aveiro, Aveiro, Portugal
PACS: 85.50.-n
Abstract
The polarization switching kinetics of ferroelectric polymer
Langmuir-Blodgett films and copolymer nanocrystals (nanomesas) was
investigated using piezoresponse force microscopy. The nanocrystals
were prepared by self-organization from Langmuir-Blodgett films of a 70%
vinylidene fluoride and 30%
trifluoroethylene copolymer. The polarization
switching time exhibits an exponential dependence on reciprocal voltage and
decreases with temperature being consistent with the nucleation switching
dynamics.