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VOLUME 90 (2009) | ISSUE 5 | PAGE 429
Magnetic and Superconducting Properties of FeAs-based High-Tc Superconductors with Gd
Abstract
We report on successful synthesis under high pressure of a series of polycristalline GdFeAs O1-xFx high-Tc superconductors with different oxigen deficiency x=0.12 \div 0.16 and also with no fluorine. We have found that the high-pressure synthesis technique is crucial for obtaining the single-phase superconducting materials: by sythesizing the same compounds with no pressure in ampoules, we obtained non-superconducting materials with an admixure of incidental phases. Critical temperature for all the materials was in the range 40 to 53 K. The temperature derivative of the critical field dHc2/dT is remarkably high, indicating potentially high value of the second critical field H_{c2} \sim 130 T.