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VOLUME 97 (2013) | ISSUE 4 | PAGE 241
Application of the two-liquid model for the interpretation of the observed electrophysical properties of supercooled water in nonopores
DOI: 10.7868/S0370274X13040103
Abstract
We propose a model combining the first-order liquid-liquid and the second-order ferroelectric phase transitions phenomenology to explain various features of the λ-point of liquid water. We suggest that the long-range dipole-dipole interaction of water molecules leads to a ferroelectric phase transition, which occurs only in the low-density component of the liquid and is the origin of the singularity of the dielectric constant recently observed in experiments with supercooled liquid water in nano-porous materials. Finally, we establish the model parameters and prove the consistency of the combined model by comparing its predictions with experimental data and the results of recent MD simulations.