Volume-charged cones on a liquid interface in an electric field
A. V. Subbotin+*, A. N. Semenov×
+A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991 Moscow, Russia
*A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, Russia
×Institut Charles Sadron, CNRS-UPR 22, Universite de Strasbourg, BP 84047, 67034 Strasbourg Cedex 2, France
Abstract
In this study we explore a novel type of slender conical liquid
meniscus arisen in high
electric field which carries surface charge and net bulk charge of opposite
sign. Stability of such
dissipative structure is ensured by the balance between capillary and
electrostatic forces and
competition between the surface and bulk electric currents. The bulk charge is
governed by the
applied voltage being generated by the electric field of the cone due to
dissociation/associations
reactions at its apex. The effect of the physical parameters of the liquid on
the micro-cone
structure is elucidated. It is shown that the cone angle can not exceed a
critical value which is a
function of dielectric permittivity of the liquid. The electric current through
the cone is found to
be proportional to the square of the applied voltage. The obtained results can
be applied for
analysis of atomization processes of various liquids.